Guides

Respiratory protection for solvents: boiling point and filter type

With solvents the filter choice hangs on one number, the boiling point. A type A filter holds back organic vapours, but only for a boiling point above 65 °C. Here you read where to find the value, which examples fall on which side of the line and what to watch with mixtures.

As of 6 October 2026, DS SafetyWear Arbeitsschutzprodukte GmbH

Why the boiling point decides

Gas filters of type A bind organic gases and vapours to activated carbon. Under EN 14387 they are tested for this when the boiling point is above 65 °C. For substances with a boiling point up to 65 °C, AX filters are intended. The AirGuard Pro range has no AX filter.

Examples: which side of the line is the substance on?

Indicative values from the GESTIS substance database. The details in the safety data sheet of your product, section 9, and the instructions for use of the filter are authoritative.
SolventBoiling point (approx.)Type A suitable?
Acetone56 °CNo, AX needed
Methanol65 °C (just below)No, AX needed
Ethyl acetate77 °CYes
Ethanol78 °CYes
Isopropanol82 °CYes
Toluene111 °CYes
Xylene (isomers)138 to 144 °CYes

Mixtures: the lowest boiling point counts

Thinners, cleaners and degreasers often consist of several solvents. Then the boiling point of the main component is not enough. If the mixture contains a substance with a boiling point up to 65 °C in a relevant amount, a type A filter does not cover that part. The safety data sheet lists the components. If in doubt, the occupational safety specialist clarifies which device is needed.

Which AirGuard Pro filters come into question

Gas filters with type A are the bayonet filters AGA1E1, AGABEKK1 and AGABEKK1P3 (each class 1, up to 0.1 % by volume). The P3 part in AGA1E1 and AGABEKK1P3 additionally holds back mist and dust, for example when spraying. You can see all filters in the filter overview.

Highest permitted gas concentration per gas filter class under DGUV Rule 112-190.
ClassMaximumAirGuard Pro
Class 10.1 % by volume (1,000 ml/m³)AGA1E1, AGABEKK1, AGABEKK1P3 (bayonet)
Class 20.5 % by volume (5,000 ml/m³)AGA2E2, AGABEK2, AGABEK2P3 (RD40)
Class 31.0 % by volume (10,000 ml/m³)not in the range

Concentration and limit value

The filter goes with the question of how much solvent is in the air. The workplace exposure limit (AGW) is in TRGS 900 and in the safety data sheet. Divide the measured concentration by the AGW and you get the multiple. Up to 30 times the half mask is permitted, up to 400 times the full-face mask, each under DGUV Rule 112-190. How this works is shown in Workplace exposure limit (AGW).

What respiratory protection does not do

  • It does not protect against absorption through the skin. Some solvents enter the body this way too. Gloves and protective clothing belong with it.
  • A half mask does not protect the eyes. With irritating vapours or splashes the full-face mask AG700 is the right choice.
  • It does not replace ventilation or extraction. These measures come first.

If you know substance and concentration, the respirator finder leads to the matching combination.

Frequently asked questions

Which respirator filter protects against acetone?

Acetone boils at about 56 °C. AX filters are intended for it, not type A. The AirGuard Pro range has no AX filter. For acetone contact us or the occupational safety specialist.

Does an A filter protect against toluene and xylene?

Yes. Toluene (about 111 °C) and xylene (about 138 to 144 °C) are above 65 °C. The exact suitability is in the safety data sheet of the product and in the instructions for use of the filter.

Where do I find the boiling point of a solvent?

In the safety data sheet, section 9, or in the GESTIS substance database. For mixtures it states the boiling range.

Which gas filter class do I need for solvents?

That depends on the concentration. Class 1 applies up to 0.1 % by volume (1,000 ml/m³). Higher classes are permitted only according to the instructions for use of the respective filter and at a known concentration.

Sources

For purchasing and occupational safety

Not sure what suits your workplace?

Send us the activity and the substances per safety data sheet. We advise on selection and send samples for a wearing trial.

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